Your Yotta debit card can be used anywhere that MasterCard is accepted. There is a 1% ISA fee for foreign transactions, and the merchant or MasterCard may charge conversion or other fees.
There are some countries where you won't be able to use your debit card at ATMs or with merchants, and the card transactions will decline:
Central African Republic
Democratic Republic of Congo
Democratic People's Republic of Korea (a.k.a. North Korea)